Recent Publications

Publications 2022

C. Ni, X. Ma, Z. Yang, H. W. Roesky
Europ. J. Inorg. Chem. 2022, (10), 1-15
https://doi.org/10.1002/ejic.202100929
Recent advances in aluminum compounds for catalysis

A. Kumar, S. Banerjee, N. Sharma, M. Nazish, N. Graw,
R. Herbst-Irmer, D. Stalke, U. Lourderaj, H.W. Roesky
Dalton Trans. 2022, 51, 4898-4902
DOI: 10.1039/d2dt00317a
Synthesis and computational aspects of Al(II)–Al(II) and Ga(II)–Ga(II) dihalides based on an amidinate scaffold

S. K. Kushvaha, A. Mishra, H. W. Roesky, K. C. Mondal
Chem. Asian J. 2022, 17(7), 1-48
https://onlinelibrary.wiley.com/doi/epdf/10.1002/asia.202101301
Recent Advances in the Domain of Cyclic (Alkyl)(Amino) Carbenes

Yilin Chen, Zhikang Chen, Liuyin Jiang, Jiancheng Li, Yiling Zhao, Hongping, Zhu, Herbert W. Roesky
One‐ and Two‐Electron Transfer Oxidation of 1,4‐Disilabenzene with Formation of Stable Radical Cations and Dications
Chem. Eur. J. 2022, 28(5), 1-9
https://doi.org/10.1002/chem.202103715

Ekta Nag, Aditya Kulkarni, Sai Manoj, N. V. T. Gorantla, Nico Graw, Maria Francis, Regine Herbst-Irmer, Dietmar Stalke, Herbert W. Roesky, Kartik Chandra Mondal, Sudipta Roy Fluorescent organo-antimony compounds as precursors for syntheses of redox-active trimeric and dimeric alkali metal antimonides: an insight into electron transfer reduction processes
Dalton Transactions 2022, 51(5), 1791-1805
https://pubs.rsc.org/en/content/articlepdf/2022/dt/d1dt03398k

S. Ralbangshi, S. Ghosh, G. Hogarth, Vo.V. Nesterov, Vi. N. Nesterov, M. G. Richmond, S. E. Kabir, H. W. Roesky
Sterochemical control of the diphosphine and alkyne ligands in triruthenium clusters: the effect of reversible CO loss/addition on the ligand distribution in [Ru3,(μ3ɳ2-PhCCPh){μ-Ph2PCH(Me)PPh2}(CO)7,8]
J. Organomet. Chem. 2022, 968-969: 122337
https://doi.org/10.1016/j.jorganchem.2022.122337
https://www.sciencedirect.com/science/article/abs/pii/S0022328X22000857

B. Yan, S. Dutta, X. Ma, C. Ni, D. Koley, Z. Yang, H. W. Roesky
Organoaluminum hydrides catalyzed hydroboration of carbonates, esters, carboxylic acids and carbon dioxide
Dalton Transaction 2022, 51, 6756-6765
DOI: 10.1039/D2DT00785A

S. Kumar Sarka, S. Kundu, M. Nazish, J. Kretsch, R. Herbst‐Irmer, D. Stalke, Parameswaran Parvathy; Pattiyil Parameswaran, H. W. Roesky
A carbene-stabilized boryl-phosphinidene
Chemistry – A European Journal 2022, 28,e202200913
DOI: 10.1002/chem.202200913

M. Nazish, Y. Ding, C. M. Legendre, A. Kumar, N. Graw, B. Schwederski, R. Herbst-Irmer, P. Parvathy, P. Parameswaran, D. Stalke, W. Kaim, H. W. Roesky
Excellent yield of a variety of slicon-boron radicals and their reactivity
Dalton Trans. 2022, 51, 11040-11047

M. Nazish, H. Bai, M. Legendre, R. Herbst-Irmer, L. Zhao,
D. Stalke, H.W. Roesky
A neutral vicinal silylene/phosphane supported six-membered C2PSiAu2 ring and a silver(I) complex
Chem.Commun. 2022, 12704-12707

B. Wang, Y. Zhuang, D. Tu, L. Shen, Zheng-Feng Zhang, Ming-Der Su, Yan Li, Di Wu, H. W. Roesky
Deoxygenation Reduction of CO2 by [Cp+Al4 ] to form (Al3O2C)2 cluster featuring two ketene moieties
Inorg.Chem. 2022, 61,14500-14506

Y. Ding, S. K. Sarkar, M. Nazish, P. Niklas Ruth, R. Herbst-Irmer, S. Muhammed, P. Parameswaran, D. Stalke, H. W. Roesky
Insertion Reaction of Me3SiN3 with Bis(germylene)
Inorg. Chem. 2022, 61, 19067-19074
https://doi.org/10.1021/acs.inorgchem.2c02252.

Shuai-Cong Huo, Yao Li, De-Xiang, Qi Zhou, Ying Yang, H.W. Roesky
Synthesis, characterization, and reaction of digermylenes
Chem. Asian J.2022, 17, e202200141

M. Nazish, Han Bai, C. M. Legendre, R. Herbst-Irmer, Lili Zhao, D. Stalke, H.W. Roesky
A neutral silylene/phosphane supported six-membered C2PSiAu2 ring and a silver(I) complex
Chem. Commun. 2022 ,DOI:10.1039/d2cc04163d

Publications 2023

M.L. Bhowmik, Md. Abdullah Al Mamun, S. Ghosh, V. N. Nesterov, M.G. Richmond, Shariff E. Kabir, H. W. Roesky
Polynuclear ruthenium clusters containing stibine, stibene, and stibinidene ligands
J. Organomet. Chem. 2023, 948, 122574
https://doi.org/10.1016/j.jorganchem.2022.122574

F. Islam, Md. Sohag Hasan, S. Ghosh, M.G. Richmond,
S. E. Kabir, H. W. Roesky
Reactions of diphosphine-stabilized Os3 clusters with triphenylantimony: syntheses and structures of new antimony-containing Os3 clusters via Sb-Ph bond cleavage
RSC.Adv. 2023, 13, 2841-2851

S.C. Huo, Yao Li, Peng-Fei Ji, De-Xiang Zhang, Zhi-Jiao Zhang, Ying Yang, H. W. Roesky
β- Diketiminate Aluminum dihydride is a valuable precursor for the preparation of acyclic and cyclic systems
Z. Anorg.Allg. Chem. 2023, 649, e202200279
https://onlinelibrary.wiley.com/doi/10.1002/zaac.202200279

M. Nazish, C. M. Legendre, N. Graw. R. Herbst-Irmer, D. Stalke, S. Sankar Dutta, Upakarasamy, Lourderaj, H. W. Roesky
Coordination and stabilization of a lithium ion with a silylene
Chem.Eur. J. 2023, e202203528

M. Nazish, C. M. Legendre, N. Graw, R. Herbst- Irmer, Shahila Muhammed, Pattiyl Parameswaran, D. Stalke, H. W. Roesky
Compounds with alternating single and double bonds of antimony and silicon; isoelectronic to ethane-1,2-diimine
Inorg.Chem. 2023,, 62, 24, 9306-9313

M. Nazish, A. Harinath, D. Lüert, C. Köhler, R. Herbst- Irmer, D. Stalke, H.W. Roesky
Reactivity of silylene with gallium- and boron trihalide at reductive conditions resulting in unforeseen products
Chem. Eur. J. 2023, e 202300310

Yi Ding, M. Nazish, P.N. Ruth, R. Herbst-Irmer, D. Stalke, H.W.Roesky
One silicon atom of bis(silylene) functions as a selective Lewis base under adduct formation with a Lewis acid
Dalton Trans. 2023, 52, 6175-6179



M. Nazish, C. M. Legendre, R. Herbst-Irmer, S. Muhammed, P. Parameswaran, D. Stalke, H.W. Roesky
Synthesis and Characterization of substituted Phosphasilenes and its rare homologue stibasilene Si=Sb-
Chem.Eur. J. 2023, e202300791 (1 of 5)

Shuai-Cong Hua, Yao Li, Peng-Fei Ji, De-Xiang, Ying Yang, H.W. Roesky
Interaction of germanium analogue of organic isonitrile with Cu(I) imide in side-on-mode
Dalton Trans. 2023, 52, 10672-10676

A. Kumar, K. Yadav, N. Graw, M. K. Pandey, R. Herbst –Irmer, U. Lourderaj, D. Stalke, H.W.Roesky
[2+4] Cycloaddition product of an amidinate substituted dialumene with Toluene
Chem.Eur. J. 2023, 29, e202300546

M. Asif Ansari, M. Ansari, M. K. Pandey, C. Köhler, R. Herbst-Irmer, D. Stalke, H.W. Roesky
Divers reactivity of bis(silylene and bis(germylene) [LE-LE (E=Si and Ge: L= PhC(NtBu)2)] in the oxidative activation of C-F bond: Si-Si bond has retained while the Ge-Ge bond is cleaved
Europ. J. Inorg. Chem. 2023, 26, 10.1002
/eijic.202300209. https://doi.org/10.1002/ejic.202300209