Publications
2024
(385) Isostructural Series of a Cyclometalated Iron Complex in Three Oxidation States
JJ. Steube, L. Fritsch, A. Kruse, O. S. Bokareva, S. Demeshko, H. Elgabarty, R. Schoch, M. Alaraby, H. Egold, B. Bracht, L. Schmitz, S. Hohloch, T. D. Kühne, F. Meyer, O. Kühn, S. Lochbrunner, M. Bauer Inorg. Chem. 2024, 63, 16964−16980
(384) Out-of-equilibrium dynamics of a grid-like Fe(II) spin crossover dimer triggered by a two-photon excitation
J. de Jesus Velazquez-Garcia, K. Basuroy, J. Wong, S. Demeshko, F. Meyer, I. Kim, R. Henning, Y. U. Staechelin, H. Lange, S. Techert Chem. Sci. 2024, 15, 13531–13540
(383) Cooperative Sulfur Transformations at a Dinickel Site: A Metal Bridging Sulfur Radical and Its H‑Atom Abstraction Thermochemistry
V. Tagliavini, P.-C. Duan, S. Chatterjee, E. Ferretti, S. Dechert, S. Demeshko, L. Kang, S. Peredkov, S. DeBeer, F. Meyer J. Am. Chem. Soc. 2024, 146, 23158−23170
(382) Record Quantum Tunneling Time in an Air-Stable Exchange-Bias Dysprosium Macrocycle
Z. Zhu, S. Paul, C. Zhao, J. Wu, X. Ying, L. Ungur, W. Wernsdorfer, F. Meyer, J. Tang J. Am. Chem. Soc. 2024, 146, 18899−18904
(381) Hourglass-Shaped Homo- and Heteronuclear Nonanuclear Lanthanide Clusters: Structures, Magnetism, Photoluminescence, and Theoretical Analysis
P. Pandey, D. Chauhan, M. G. Walawalkar, S. K. Gupta, F. Meyer, G. Rajaraman, R. Murugavel Inorg. Chem. 2024, 63, 11963−11976
(380) Ferromagnetically Coupled Chromium(III) Dimer Shows Luminescence and Sensitizes Photon Upconversion
S. Trippmacher, S. Demeshko, A. Prescimone, F. Meyer, O. S. Wenger, C. Wang Chem. Eur. J. 2024, 30, e202400856
(379) Gradual solid-state redox-isomerism in the lanthanide series
D. A. Lukina, A. A. Skatova, R. V. Rumyantcev, S. V. Demeshko, F. Meyer,
I. L. Fedushkin Dalton Trans. 2024, 53, 9119−9128
(378) Chromium−Thiolate Complex Undergoing C−S Bond Cleavage
K. Shen, M. Gennari, C. Philouze, A. Velić, S. Demeshko, F. Meyer, C. Duboc Inorg. Chem. 2024, 63, 9119−9128
(377) Testing functional anchor groups for the efficient immobilization of molecular catalysts on silver surfaces
O. Bunjes, A. Rittmeier, D. Hedman, S.-A. Hua, L. A. Paul, F. Meyer, F. Ding, M. Wenderoth Communications Chemistry 2024, 7, 107
(376) Iron(III) Carbene Complexes with Tunable Excited State Energies for Photoredox and Upconversion
J. Wellauer, F. Ziereisen, N. Sinha, A. Prescimone, A. Velić, F. Meyer, O. S. Wenger J. Am. Chem. Soc. 2024, 146, 11299−11318
(375) Bifurcation of Excited-State Population Leads to Anti-Kasha Luminescence in a Disulfide-Decorated Organometallic Rhenium Photosensitizer
J. Franz, M. Oelschlegel, J. P. Zobel, S.-A. Hua, J.-H. Borter, L. Schmid, G. Morselli, O. S. Wenger, D. Schwarzer, F. Meyer, L. González J. Am. Chem. Soc. 2024, 146, 11272−11288
(374) Synthesis and Reactivity of a Dialane-Bridged Diradical
D. Dhara, L. Endres, I. Krummenacher, M. Arrowsmith, R. D. Dewhurst, B. Engels, R. Bertermann, M. Finze, S. Demeshko, F. Meyer, F. Fantuzzi, H. Braunschweig Angew. Chem. Int. Ed. 2024, 63, e202401052
(373) Oxygen-Donor Metalloligands Induce Slow Magnetization Relaxation in Zero Field for a Cobalt(II) Complex with {CoO4} Motif
G. Lococciolo, S. K. Gupta, S. Dechert, S. Demeshko, C. Duboc, M. Atanasov, F. Neese, F. Meyer Inorg. Chem. 2024, 63, 5652−5663
(372) Construction of Diiron Diamond-Core Complexes Influenced by a Fluoroalkoxide Ligand
M. A. Chacon-Teran, S. E. Creutz, R. E. Rodriguez-Lugo, S. Demeshko, F. Meyer,
A. Kajetanowicz, K. Grela Organometallics 2024, 43, 564−572
(371) Spin-state versatility in Fe4IIL6 supramolecular cages with a pyridyl-hydrazone ligand scaffold modulated by solvents and counter anions
W. Li, X. Li, K. Robeyns, M. Wolff, J. Kfoury, J. Oláh, R. Herchel, S. Demeshko, F. Meyer, Y. Garcia
Dalton Trans. 2024, 53, 1449–1459
2023
(370) Tuning Magnetic Anisotropy in Co(II) Tetrahedral Carbazole-Modified Phosphine Oxide Single-Ion Magnets: Importance of Structural Distortion versus Heavy-Ion Effect
G. Bhatt, T. Sharma, S. K. Gupta, F. Meyer, G. Rajaraman, R. Murugavel Inorg. Chem. 2023, 62, 18915−18925
(369) Nonheme FeIV═O Complexes Supported by Four Pentadentate Ligands: Reactivity toward H- and O- Atom Transfer Processes
Y. Li, R. Singh, A. Sinha, G. C. Lisensky, M. Haukka, J. Nilsson, S. Yiga, S. Demeshko, S. J. Gross, S. Dechert, A. Gonzalez, G. Farias, O. F. Wendt, F. Meyer, E. Nordlander Inorg. Chem. 2023, 62, 18338−18356
(368) A low-coordinate iron organoazide complex
A. Gonzalez, S. Demeshko, F. Meyer, C. G. Werncke Chem. Commun. 2023, 59, 11532–11535
(367) Structural dynamics of a thermally silent triiron(II) spin crossover defect grid complex
J. de J. Velazquez-Garcia, K. Basuroy, D. Storozhuk, J. Wong, S. Demeshko, F. Meyer, R. Henning, S. Techert Dalton Trans. 2023, 52, 12224–12234
(366) From a mononuclear FeIIL2 complex to a spin crossover FeII4L6 cage by symmetric ligand architecture modification: insights into the ammonia gas sensing mechanism
W. Li, A. Rotaru, M. Wolff, S. Demeshko, F. Meyer, Y. Garcia J. Mater. Chem. C 2023, 11, 11175–11184
(365) Cu4S Cluster in "0-Hole" and "1-Hole" States: Geometric and Electronic Structure Variations for the Active CuZ* Site of N2O Reductase
Y. Liu, S. Chatterjee, G. E. Cutsail III, S. Peredkov, S. K. Gupta, S. Dechert, S. DeBeer, F. Meyer J. Am. Chem. Soc. 2023, 145, 18477−18486
(364) Tailoring activity and stability: Effects of electronic variations on iron-NHC epoxidation catalysts
T. P. Schlachta, G. G. Zámbó, M. J. Sauer, I. Rüter, C. A. Hoefer, S. Demeshko, F. Meyer, F. E. Kühn Journal of Catalysis 2023, 426, 234–246
(363) Chemical Synthesis of Alpha-Synuclein Proteins via Solid-Phase Peptide Synthesis and Native Chemical Ligation
L. M. Gatzemeier, F. Meyer, U. Diederichsen, T. F. Outeiro Chem. Eur. J. 2023, 29, e202300649
(362) Synthesis, Properties, and Reactivity of a Linear NHC-Based Chromium(I) Silylamide
A. Gonzalez, T.-Y. Chen, S. Demeshko, F. Meyer, C. G. Werncke Organometallics 2023, 42, 1198−1204
(361) Air-stable four-coordinate cobalt(II) single-ion magnets: experimental and ab initio ligand field analyses of correlations between dihedral angles and magnetic anisotropy
S. K. Gupta, S. V. Rao, S. Demeshko, S. Dechert, E. Bill, M. Atanasov, F. Neese, F. Meyer Chem. Sci. 2023,14, 6355–6374
(360) Ligand Modulation of the Structures and Magnetic Relaxation in Triangular Dy3 Complexes Based on a Tricompartmental Scaffold
J. Wu, F. Zhang, G.-L. Wang, S. Demeshko, S. Dechert, Y.-Q. Zhang, F. Meyer Chem. Eur. J. 2023, 29, e202203494
(359) Janus-type emission from a cyclometalated iron(iii) complex
J. Steube , A. Kruse , O. S. Bokareva , T. Reuter, S. Demeshko, R. Schoch, M. A. Argüello Cordero , A. Krishna , S. Hohloch , F. Meyer , K. Heinze , O. Kühn, S. Lochbrunner , M. Bauer Nature Chemistry 2023, 15, 468−474
(358) Multi-Technique Experimental Benchmarking of the Local Magnetic Anisotropy of a Cobalt(II) Single-Ion Magnet
S. K. Gupta, H. H. Nielsen, A. M. Thiel, E. A. Klahn, E. Feng, H. B. Cao, T. C. Hansen, E. Lelièvre-Berna, A. Gukasov, I. Kibalin, S. Dechert, S. Demeshko, J. Overgaard, F. Meyer JACS Au 2023, 3, 429−440
(357) Fully Delocalized Mixed-Valent Cu1.5Cu1.5 Complex: Strong Cu-Cu interaction and Fast Electron Self-Exchange Rate Despite Large Structural Changes
Y. Liu, S. G. Resch, H. Chen, S. Dechert, S. Demeshko, E. Bill, S. Ye, F. Meyer Angew. Chem. Int. Ed. 2023, 62, e202215840
(356) On the Single-Molecule Magnetic Behavior of Linear Iron(I) Arylsilylamides
R. Weller, M. Atanasov, S. Demeshko, T.-Y. Chen, I. Mohelsky, E. Bill, M. Orlita, F. Meyer, F. Neese, C. G. Werncke Inorg. Chem. 2023, 62, 3153−3161
(355) Iodoarene mediated efficient aerobic oxidation of aldehydes for carboxylic acids
K. Zeng, A. C. Stückl, J. Qin, M. Simon, C.-J. Spyra, J. Li, F. Meyer, K. Zhang Molecular Catalysis 2023, 537, 112919
(354) Ruthenium Complexes of Rigid, Dianionic, Tetradentate N-Donor Ligands and their Potential as Catalysts for Water Oxidation
S. Rajabi, F. Rüttger J. Lücken, S. Dechert, M. John, F. Meyer Eur. J. Inorg. Chem. 2023, 26, e202200597
2022 More
(353) Short- vs. long-range elastic distortion: structural dynamics of a [2 × 2] tetrairon(II) spin crossover grid complex observed by time-resolved X-Ray crystallography
J. de Jesus Velazquez-Garcia, K. Basuroy, D. Storozhuk, J. Wong, S. Demeshko, F. Meyer, R. Henning, S. Techert Dalton Trans. 2022, 51, 17558–17566
(352) A spin crossover FeII4L6 cage based on pyridyl-hydrazone sites
W. Li, C. Liu, J. Kfoury, J. Oláh, K. Robeyns, M. L. Singleton, S. Demeshko, F. Meyer, Y. Garcia Chem. Commun. 2022, 58, 11653–11656
(351) Borylation in the Second Coordination Sphere of FeII Cyanido Complexes and Its Impact on Their Electronic Structures and Excited-State Dynamics
L. Schmid, P. Chábera, I. Rüter, A. Prescimone, F. Meyer, A. Yartsev, P. Persson, O. S. Wenger Inorg. Chem. 2022, 61, 15853−15863
(350) Luminescent Iridium Complexes with a Sulfurated Bipyridine Ligand: PCET Thermochemistry of the Disulfide Unit and Photophysical Properties
M. Oelschlegel, S.-A. Hua, L. Schmid, P. Marquetand, A. Bäck, J.-H. Borter, J. Lücken, S. Dechert, O. S. Wenger, I. Siewert, D. Schwarzer, L. González, F. Meyer Inorg. Chem. 2022, 61, 13944–13955,
(349) Between imide, imidyl and nitrene –an imido iron complex in two oxidation states
S. Reith, S. Demeshko, B. Battistella, A. Reckziegel, C.Schneider, A. Stoy, C. Lichtenberg, F. Meyer, D. Munz, C. G. Werncke Chem. Sci. 2022, 13, 7907–7913
(348) Antisymmetric Spin Exchange in a μ‑1,2-Peroxodicopper(II) Complex with an Orthogonal Cu−O−O−Cu Arrangement and S = 1 Spin Ground State Characterized by THz-EPR
T. Lohmiller, C.-J. Spyra, S. Dechert, S. Demeshko, E. Bill, A. Schnegg, F. Meyer JACS Au. 2022, 2, 134−1143.
(347) Organometallic μ‑Nitridodiiron Complexes in Oxidation States Ranging from (III/III) to (IV/IV)
C. Cordes (née Kupper), I. Klawitter, I. Rüter, S. Dechert, S. Demeshko, S. Ye, F. Meyer Inorg. Chem. 2022, 61, 7153−7164.
(346) Polynuclear Iron(II) Pyridonates: Synthesis and Reactivity of Fe4 and Fe5 Clusters
A. Fedulin, S. K. Gupta, I. Rüter, F. Meyer, A. Jacobi von Wangelin Inorg. Chem. 2022, 61, 6149−6159.
(345) Solar Light-Assisted Oxidative Degradation of Ciprofloxacin in Aqueous Solution by Iron(III) Chelated Cross-Linked Chitosan Immobilized on a Glass Plate
S. Saha, T. Kumar Saha, S. Karmaker, Z. Islam, S. Demeshko, H. Frauendorf, F. Meyer Catalysts. 2022, 12, 475.
(344) Iron(III) Complexes of a Hexadentate Thioether-Appended 2 Aminophenol Ligand: Redox-Driven Spin State Switchover
A. Ali, S. Bhowmik, S. K. Barman, N. Mukhopadhyay, C. E. Glüer (née Schiewer), F. Lloret, F. Meyer, R. Mukherjee Inorg. Chem. 2022, 61, 5292−5308.
(343) Metal-to-metal communication during the spin state transition of a [2 × 2] Fe(II) metallogrid at equilibrium and out-of-equilibrium conditions
J. de Jesus Velazquez-Garcia, K. Basuroy, D. Storozhuk, J. Wong, S. Demeshko, F. Meyer, R. Henning, S. Techert Dalton Trans. 2022, 51, 6036–6045.
(342) Combining Valence-to-Core X‑ray Emission and Cu K‑edge X‑ray Absorption Spectroscopies to Experimentally Assess Oxidation State in Organometallic Cu(I)/(II)/(III) Complexes
B. L. Geoghegan, Y. Liu, S. Peredkov, S. Dechert, F. Meyer, S. DeBeer, G. E. Cutsail III J. Am. Chem. Soc. 2022, 144, 2520−2534.